They pretty much all suck air, so I would get a pack of vinyl vacuum pipe caps from the auto parts store and plug them all, including the ones on your vacuum tree that should be coming out the back of your carb. Some will be "manifold" vacuum, which have vacuum all the time when running, and some are "ported" vacuum, which don't have vacuum until the throttle valve is at a certain angle. So, if you just plug them off now, the car will run well, and you can connect the appropriate hoses to them later. The vacuum tree behind the carb is manifold vacuum. The secondary vacuum break, which is the can on the back of the carb that you're asking about, should be connected to manifold vacuum. So, connect it to one of the ports off your vacuum tree behind the carb. Also, that black line laying loose under your choke is for vacuum to your heat/ac panel on the dash, so plug it also to one of the ports off your rear vacuum tree.
There are diagrams in the emissions section of the Pontiac service manual for your car that show where the hoses go and which ports on the carb are manifold and which are ported.